瀹為獙瀹ゆ柊闂?/h4>
鐜嬪墤娉㈣棰樼粍涓庡悎浣滆�呭湪閽偓鍖栫殑鍗″鍋惰仈浠ュ強C1鑱氬悎棰嗗煙鍙栧緱鏂拌繘灞?/h1>
浣滆�咃細
鏉ユ簮锛?nbsp;
鍙戝竷鏃ユ湡:2021-12-24
鍩轰簬閲戝睘鍗″鐨勫偓鍖栧弽搴旓紝鐗瑰埆鏄氦鍙夊伓鑱斿弽搴旇繎骞存潵鍙戝睍杩呴�燂紝鍖椾含澶у鍖栧涓庡垎瀛愬伐绋嬪闄?/span>鐜嬪墤娉㈣棰樼粍鍦ㄧ浉鍏抽鍩熷紑灞曚簡涓�绯诲垪鐮旂┒宸ヤ綔锛?/span>Acc. Chem. Res. 2013, 46, 236; Chem. Rev. 2017, 117, 13810.锛夈�傝繖浜涘伓鑱斿弽搴旂殑鍏抽敭姝ラ鏄崱瀹剧殑杩佺Щ鎻掑叆锛岃�屾嫇灞曡縼绉诲熀鍥㈡槸璇ラ鍩熻繘涓�姝?/span>鍙戝睍鐨勬牳蹇冦�傝繎鏈燂紝浠栦滑瀹炵幇浜嗗惈纭煎熀鍥?/span>鐨?/span>杩佺Щ锛?/span>寤虹珛浜嗗熀浜庡崱瀹惧伓鑱旂殑纭煎寲鍙嶅簲鏂版柟娉曘�傝鍙嶅簲搴旂敤閽?/span>鍌寲鍓傦紝缁忚繃閰?/span>琛嶇敓鐨?/span>瀵圭敳鑻?/span>纾?/span>閰?/span>鑵?/span>涓庤仈纭艰瘯鍓傜殑姘у寲鍋惰仈鍚?/span>鎴愮儻鍩虹〖閰?/span>銆?/span>鐑熀纭奸叝鏄?/span>涓�绫婚噸瑕佺殑鏈夋満鍚堟垚涓棿浣擄紝鍏堕珮鏁堛�侀珮閫夋嫨鎬х殑鍚堟垚鍏锋湁鍗佸垎閲嶈鐨勬剰涔夈�傚拰缁忓吀鐨勯叜缁忕敱鐑熀涓?/span>姘?/span>鐢?/span>纾洪吀閰湪閽偓鍖栦笅鍜?/span>鑱旂〖璇曞墏鍋惰仈锛?/span>Miyaura纭煎寲锛夌殑鏂规硶鐩告瘮锛屽崱瀹惧伓鑱旂殑鏂版柟娉曞叿鏈変竴瀹氱殑浼樺娍鎴?/span>浜掕ˉ鎬?/span>锛?/span>J. Am. Chem. Soc. 2021, 143, 9769.锛?/span>銆?/span>
鍥?/span>1. 閽偓鍖栨哀鍖栧伓鑱斿悎鎴愮儻鍩虹〖閰?/span>
鐜嬪墤娉?/span>璇鹃缁?/span>鍦ㄥ崱瀹惧伓鑱旂爺绌舵柟闈㈢殑鍙︿竴椤归噸瑕佽繘灞曟槸閽偓鍖栫殑鍗″瀵圭⒊纭呴敭鐨勪笉瀵圭О鎻掑叆鍙嶅簲銆?/span>鍚鏈夋満鍖栧悎鐗╁湪鍖昏嵂锛屾潗鏂欑瓑棰嗗煙鍏锋湁骞挎硾搴旂敤锛屽洜姝ゅ浣曢珮鏁堛�侀珮閫夋嫨鎬у湴鏋勫缓纰崇閿槸閲嶈鐨勭爺绌惰棰樸�?/span>杩囨浮閲戝睘鍌寲鐨勫崱瀹惧Si-H閿殑鎻掑叆鍙嶅簲鏄瀯寤虹⒊纭呴敭鐨勪竴绉嶇畝鍗曢珮鏁堢殑鏂规硶锛?/span>鍥犳鐩稿簲鐨勫崱瀹惧Si-C閿殑鎻掑叆鏃犵枒鏄彟澶栦竴绉嶆柊棰栭珮鏁堢殑鏋勫缓纰崇閿殑鏂规硶銆傜劧鑰岋紝杩?/span>绉嶇被鍨嬬殑鍌寲鍙嶅簲鑷充粖鏈浘瀹炵幇锛屽叾瀵规槧閫夋嫨鎬ф帶鍒跺皢浼氭槸鏇村ぇ鐨勬寫鎴樸�?/span>璇ョ爺绌跺洟闃?/span>閲囩敤鍒嗘鐨?/span>鈥?/span>姘у寲鍔犳垚-鍗″杞Щ鎻掑叆-杩樺師娑堥櫎鈥?/span>绛栫暐鎴愬姛瀹炵幇浜嗛挴鍌寲鐨勫崱瀹惧纰崇閿殑涓嶅绉版彃鍏ワ紝涓哄惈鏈変笁绾ф垨鍥涚骇鎵嬫�?/span>纰充腑蹇冪殑纭呮潅鐜垔鐑风殑鍚堟垚鎻愪緵浜嗕竴绉嶆柊棰栭珮鏁堢殑鏂规硶銆傞�氳繃DFT鐞嗚璁＄畻锛屽鍙嶅簲鏈虹悊鍙婃帶鍒剁珛浣撻�夋嫨鎬х殑鍏抽敭鍥犵礌杩涜浜嗘繁鍏ョ殑鎺㈣锛?/span>J. Am. Chem. Soc. 2021, 143, 12968.锛夈�?/span>
鍥?/span>2. 閽偓鍖栧崱瀹惧纰崇閿殑涓嶅绉版彃鍏ュ弽搴?/span>
闄や簡鍦ㄦ湁鏈哄悎鎴愪腑鐨勫簲鐢ㄥ锛岄挴鍗″鐨勮縼绉绘彃鍏ヤ篃鏄崱瀹?/span>C1鑱氬悎鐨勫叧閿楠ゃ�?/span>C1 鑱氬悎鍙互寰楀埌涓婚摼鐢辩⒊纰?/span>鍗曢敭鏋勬垚鐨勮仛鍚堢墿锛屽彈鍒颁汉浠殑鍏虫敞銆傚叾涓紝閲嶆爱涔欓吀閰殑C1鑱氬悎琚箍娉涚爺绌讹紝瀹?/span>鍙互寰楀埌涓婚摼姣忎釜纰冲師瀛愰兘琚叝鍩?/span>鍙栦唬鐨勮仛鍚堢墿锛岃繖绫昏仛鍚堢墿閫氳繃浼犵粺鐨勭儻鐑冮厤浣嶈仛鍚堟棤娉曞悎鎴愩�?/span>鍦ㄨ繎鏈熺殑鐮旂┒涓?/span>锛岀帇鍓戞尝璇鹃缁?/span>鍙戝睍浜嗕竴绉嶆柊鐨勫紩鍙戜綋绯伙紝(鐜垔浜岀儻鍩?/span>)(鐑笝鍩?/span>)閽?/span>[Cp(蟺-allyl)Pd]锛?/span>鍙互楂樻晥鍦板疄鐜伴噸姘箼閰搁叝鐨勯摼寮忚仛鍚堛�傝鑱氬悎浣撶郴鍙互鍏煎涓嶅悓鐨勭兎鍩恒�佽姵鍩轰互鍙婃椿娉煎畼鑳藉洟鍙栦唬鐨勫崟浣擄紝骞朵笖鍙互鏂逛究鍦板疄鐜拌仛鍚堢墿鐨?/span>鍚庝慨楗般�?/span>
鍥?/span>3. 閽偓鍖栫殑鍗″鑱氬悎
鍔ㄥ姏瀛︾爺绌惰〃鏄庡湪鑱氬悎鍙嶅簲鐨勫垵鏈燂紝鍒嗗瓙閲忓氨澧為暱鍒版渶澶у�硷紝骞朵笖闅忕潃杞寲鐜囩殑澧炲姞锛屼竴鐩翠繚鎸佸湪鏈�澶у�奸檮杩戯紝璇存槑鍙嶅簲鍏锋湁鎱㈠紩鍙戙�?/span>蹇闀?/span>鐨勭壒鐐广�傝鍙嶅簲涓庡崟浣撳憟鐜颁竴绾у姩鍔涘鍏崇郴銆傛澶栵紝杩樺彂鐜板綋鍚?/span>鍙嶅簲浣撶郴涓姞鍏ユ按鎴栬�呭皬鍒嗗瓙閱?/span>绫绘椂锛岃仛鍚堢墿鍒嗗瓙閲忔槑鏄句笅闄嶃�傚悜浣撶郴涓姞鍏ヤ笉鍚屾祿搴︾殑涔欓唶鏃讹紝鍙互寰楀埌涓嶅悓鍒嗗瓙閲忕殑鑱氬悎鐗┿�傞殢鐫�涔欓唶娴撳害鐨勫鍔狅紝鑱氬悎鐗╁垎瀛愰噺鍛堢幇閫愭笎涓嬮檷鐨勮秼鍔匡紝骞朵笌鑱氬悎搴︾殑鍊掓暟鍛堢幇绾垮舰鍏崇郴銆傞�氳繃MALDI-TOF-MS 杩涗竴姝ヨ瘉瀹烇紝褰撳姞鍏ヤ箼閱囨椂锛屽緱鍒扮殑鑱氬悎鐗?/span>鐨勭鍩哄垎鍒?/span>鏄箼姘у熀鍜?/span>姘?/span>銆備互涓婄粨鏋滆鏄庝箼閱囧彲浠ヤ綔涓洪摼杞Щ璇曞墏锛岄�氳繃璋冩帶涔欓唶鐨勬祿搴﹀彲浠ュ緱鍒颁笉鍚屽垎瀛愰噺鐨勮仛鍚堢墿銆?/span>閫氳繃涓婅堪瀹為獙锛?/span>璇ュ洟闃?/span>鎻愬嚭浜嗙浉搴旂殑鍙嶅簲鏈虹悊锛?/span>Macromolecules 2021, 54, 10914.锛夈�?/span>
鍥?/span>4. 涔欓唶瀵硅仛鍚堢墿鍒嗗瓙閲忕殑褰卞搷浠ュ強鑱氬悎鍙嶅簲鏈虹悊
浠?/span>涓?/span>璁烘枃鐨勭涓�浣滆�呭垎鍒负鍖椾含澶у鍖栧涓庡垎瀛愬伐绋嬪闄?/span>2016绾?/span>鍗氬＋鐮旂┒鐢?/span>骞充竴鍑°�?/span>鍗氶泤鍗氬＋鍚?/span>闇嶉潤鍑や互鍙?/span>2016绾?/span>鍗氬＋鐮旂┒鐢?/span>濮氬叴濂?/span>銆傜帇鍓戞尝鏁欐巿銆侀浄楦ｆ暀鎺堬紙鍖椾含鍖栧伐澶у锛夊拰钃濆畤鏁欐巿锛堥噸搴嗗ぇ瀛?/span>/閮戝窞澶у锛変负璁烘枃鍏卞悓閫氳浣滆�?/span>銆?/span>鐩稿叧鐨?/span>DFT鐞嗚璁＄畻鍒嗗埆鐢卞寳浜寲宸ュぇ瀛﹂浄楦ｅ洟闃熶互鍙?/span>閲嶅簡澶у/閮戝窞澶у钃濆畤鍥㈤槦瀹屾垚銆?/span>浠ヤ笂璇鹃寰楀埌鍥藉鑷劧绉戝鍩洪噾濮?/span>鍜?/span>鍖椾含鍒嗗瓙绉戝鍥藉鐮旂┒涓績鐨勮祫鍔┿�?/span>
鍘熸枃閾炬帴锛?/span>
//pubs.acs.org/doi/10.1021/jacs.1c02331